Information of Chemical Compound


JCGG-COM0000586
idDOICompoundNumberInChIKeymoleculeID
110.1002/chin.1999201677LCBFPOZEMMSKAF-KGZGDMIGSA-NN-0000-000586

idChemicalName by authormoleculeID
1N(omega)-(2-Acetamido-3,4,6-tri-O-acetyl-2-deoxy-beta-D-glucopyrano-syl)-N(alpha)-(9-fluorenylmethyloxycarbonyl)-L-asparagine tert-Butyl EsterN-0000-000586

idChemicalNamemoleculeID
1(2R,3S,4R,5R,6R)-6-(3-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)-4-(tert-butoxy)-4-oxobutanamido)-5-acetamido-2-(acetoxymethyl)tetrahydro-2H-pyran-3,4-diyl diacetateN-0000-000586

idChemicalNamemoleculeID
1(2R,3S,4R,5R,6R)-6-(3-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)-4-(tert-butoxy)-4-oxobutanamido)-5-acetamido-2-(acetoxymethyl)tetrahydro-2H-pyran-3,4-diyl diacetateN-0000-000586

idNucleusMHzSolventStandardTempTempTypeNMR_DatamoleculeID
11H NMR400CDCl3   δ = 1.44 (9H, s, t-Bu), 1.96 (3H, s,NAc), 2.04, 2.05, 2.07 (9H, three s, 3 × OAc), 2.68–2.86 (2H, m,Asn-β-CH2), 3.74–3.77 (1H, m, glc-5-H), 4.04–4.44 (6H, m, 2,6-H,Fmoc-CH2, Fmoc-CH), 4.52 (1H, m, Asn-α-CH), 5.05–5.15 (3H,m, 1,3,4-H), 5.98 (1H, d, J = 8.8 Hz, Asn-α-NH), 6.17 (1H, d, J =8.3 Hz, 2-NH), 7.20 (1H, d, J = 7.8 Hz, 1-NH), 7.30 (2H, pseudo-t,Fmoc-Ar), 7.39 (2H, pseudo-t, Fmoc-Ar), 7.60 (2H, d, J = 7.3 Hz,Fmoc-Ar), 7.75 (2H, d, J = 7.8 Hz, Fmoc-Ar)N-0000-000586

idOpticalRotationmoleculeID
1[α]27/D –1.2 (c = 1, DMSO)N-0000-000586


idStatemoleculeID
1white powderN-0000-000586